raikou cannot be caught on Pokemon ruby
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You cannot catch Raikou in Pokemon Diamond and Pearl. To get Raikou in Pokemon Diamond and Pearl, you must trade for one from Pokemon HeartGold and SoulSilver where it can be caught or transferring from Pokemon FireRed and LeafGreen.
You cant get raikou in Pokemon diamond or Pokemon pearl.But you can get him in a gba Pokemon game and transfer him to your Pokemon pearl or diamond!
Entei, Suicune, and Raikou are not available in Pokemon Emerald, Ruby or Sapphire. They can be brought into the game by trading.
You cannot get the Legendary Dogs (or Beasts such as Raikou, Suicune and Entei) in Ruby without either trading for them or cheating for them because they are not available in the wild in Ruby in any way, shape or form. But you can catch it in Pokemon Ruby Destiny-Reign of Legends. But in the original Ruby or Sapphire you can't get it.
You can catch them like suicune,raikou,and entei after you completed the National Dex or you can trade them from other games.