You can only get Volt Tackle by breeding Pikachu or Raichu with the Light Ball item attached to them however 1 of them has to be a female Pikachu or Raichu so that they can lay a Pichu Egg that will know Volt Tackle when it hatches.
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Electivire cannot learn Volt Tackle in Pokemon HeartGold. Only pichu, pikachu, and raichu can learn volt tackle.
To get the move volt tackle you need a pichu, picachu or a riachu holding a light ball then mate it with one of the Pokemon i just said but opposite sex or a ditto the bingo you have a pichu with volt tackle.
No. It is impossible without a cheat(maybe).
yes
pichu can so can pikcachu a rachiu