In Fushia City you can get a Good Rod. Fish somewhere.
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You have to use a super rod in islands 4 or 5. You can can catch it in Pokemon fire red and leaf green both.
No there is not.
you can not find him not 1 persent
You can't find a Vulpix in Pokemon FireRed version. That pokemon is version-exclusive to Pokemon LeafGreen.
Moltres is in Mt. Mortar