You can't find a Vulpix in Pokemon FireRed version. That pokemon is version-exclusive to Pokemon LeafGreen.
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Only in LeafGreen not in FireRed. Sorry.
on the roof
If you mean the old version, Pokemon Red, and not Pokemon Firered, then the only place that I can think of that have tons of fire Pokemon is the mansion on Cinnabar island. Go inside and walk around. You should find a lot of Ponyta and Vulpix, if you're playing Pokemon Blue, but if you're playing Pokemon Red, you'll more than likely find Ponyta and probably Growlithe. I'm not sure if you can find Vulpix in Pokemon Red or not. But, that's where you will find a lot of GOOD fire Pokemon. And, of course, Moltres is hidden away in Victory Road.
you can find it on route 124 I've had a vulpix and to make it evolve i had find the red shard and i had to give it to hunter in mossdep city to get the fire stone
No there is not.