Moltres is in Mt. Mortar
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you can't get him on emerald ruby or Sapphire. you have to trade him from Pokemon leaf green or fire red to emerald. on Pokemon fire red and leaf green you get him at the end of island 1.
If you mean the old version, Pokemon Red, and not Pokemon Firered, then the only place that I can think of that have tons of fire Pokemon is the mansion on Cinnabar island. Go inside and walk around. You should find a lot of Ponyta and Vulpix, if you're playing Pokemon Blue, but if you're playing Pokemon Red, you'll more than likely find Ponyta and probably Growlithe. I'm not sure if you can find Vulpix in Pokemon Red or not. But, that's where you will find a lot of GOOD fire Pokemon. And, of course, Moltres is hidden away in Victory Road.
No, you can catch Entei without catching Moltres.
moltres is in leaf green and fire red not emerald.
Moltres can't be found in Crystal. If you want it in Crystal, you'll have to use the Time Capsule or you could get it from an event in the past. You can find Moltres at Victory Road in Red/Blue/Yellow.