The way to get an Electrizer on POKeMON Pearl version is plug in a FireRed version in the GBA slot and go to Valley Windworks, in the grass their should be a few Elekids, catch them until one of them is holding an Electrizer. Then what you need to do is choose an Elekid to train, it will evolve at level 30 into an Electabuzz. Make your Electabuzz hold the Electrizer and trade it, then you will have Electavire, one of the best electric types in POKeMON history! In POKeMON Pearl there is a 50% chance of an Elekid holding an Electizer and in POKeMON Diomond there is a 5% chance of an Elekid holding one. Hope this information helps! =] P.S: Even though there is a 50% chance of getting one on POKeMON Pearl, it's still only 50% and is REALLY un-likely. (TRUST ME, I SHOULD KNOW... BUT CARRY ON AND EVENTUALLY YOU WILL FIND ONE)
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You go out and buy an Action Replay or you can make an Electabuzz hold Electirizer and trade the Electabuzz. Wild Electabuzz and Elekid can sometimes be found holding an Electirizer in Pokemon Diamond, Pearl and Platinum. You will need to use the move Trick (or a similar item-stealing move) or catch these Pokemon to get an Electirizer.
Elekids normally hold it
find an elekid and you have a 50% chance it will be holding an electirizer.
you find it bihind the bloody focking valley windworks
Have it hold an Electirizer and trade it.