Elekids normally hold it
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find an elekid and you have a 50% chance it will be holding an electirizer.
you find it bihind the bloody focking valley windworks
You go out and buy an Action Replay or you can make an Electabuzz hold Electirizer and trade the Electabuzz. Wild Electabuzz and Elekid can sometimes be found holding an Electirizer in Pokemon Diamond, Pearl and Platinum. You will need to use the move Trick (or a similar item-stealing move) or catch these Pokemon to get an Electirizer.
An item that evolves Electabuzz into Electivire when Electabuzz is traded while holding it.
breed an electabuzz if you want an elekid in Pokemon platinum