On route 212, go towards the Pokemon Mansion. Go through the gates and there is a couple on the right. The man has a Prinplup. Make your starter a chimchar and your rival will pick a piplup when you fight him eventually he will have a prinlup.
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If you chose Chimchar as your starter, your rival will eventually get a Prinplup. Also, at the Pokémon mansion, one trainer will have a Prinplup.
a few do, but if you choose infernape as your first pokemon, your rival (wally) will have piplup, that will evolve into prinplup, hope that answers your question
Here are the trainers with Prinplup and their locations:Picnicker Karina (Using the Vs. Seeker) - South of Route 205Pokemon Ranger Jeffery - South of Route 212Pokemon Trainer (Rival name and if Chimchar is chosen) - Hearthome CityPokemon Trainer Lucas/Dawn (If Turtwig is chosen) - Veilstone CityPokemon Trainer (Rival name and if Chimchar is chosen) - Pastoria CityPokemon Trainer (Rival name and if Chimchar is chosen) - Canalave City
You get prinplup when piplup evolves. To get piplup you either pick chimchar, turtwig, or piplup.
Prinplup is a Water type pokemon.