Prinplup is a Water type pokemon.
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If you chose Chimchar as your starter, your rival will eventually get a Prinplup. Also, at the Pokémon mansion, one trainer will have a Prinplup.
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Prinplup evolves into Empoleon at level 36.You can teach it Surf once you get the HM.Your prinplup will evolve on lvl 36.
you can see it just south of the Pokemon mansion on the rainy route there are two Pokemon rangers. one has an aipom one has a prinplup. but you can't get it from any one but a starter Pokemon.
You get prinplup when piplup evolves. To get piplup you either pick chimchar, turtwig, or piplup.