you can't
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level 36
Prinplup evolves into Empoleon at level 36.You can teach it Surf once you get the HM.Your prinplup will evolve on lvl 36.
breed a ditto with a piplup, a prinplup, or an empoleon. or breed 2 piplup, prinplup, or empoleon.
you carn't! you can only get it through starter pokemon. trade it OR breed a empoleon or prinplup
neither of them is better, they are both the same, but in diamond, you catch dialga, and in pearl, you catch palkia, and you can catch different Pokemon in each game for example: you can catch this Pokemon in diamond, but not pearl but: you can catch this different Pokemon in pearl, but not diamond