Here are the trainers with Prinplup and their locations:
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If you chose Chimchar as your starter, your rival will eventually get a Prinplup. Also, at the Pokémon mansion, one trainer will have a Prinplup.
you can't
level 36
a few do, but if you choose infernape as your first pokemon, your rival (wally) will have piplup, that will evolve into prinplup, hope that answers your question
Prinplup evolves into Empoleon at level 36.You can teach it Surf once you get the HM.Your prinplup will evolve on lvl 36.