Exit to the left of Sunyshore city that leads you to route 222 and the third fishermen has a finneon in his party.
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You can find a Finneon at stark Mt. To find a trainer with a Lumineon go to Sunyshore city, and the first trainer you see will have a lumineon at Lv. 38 or so.the 2nd and 3rd fishermen on route 222 have finneon
Route 222 or 224.
I don't think there is a Trainer with a Finneon, but there is a trainer with a Lumineon somewhere. You can find a Finneon on Route 205 South, Route 218, Route 219, Route 220, Route 221, Canalave City, the Valley Windworks, and the Fuego Ironworks. You can also find a Finneon in Iron Island if you fish with the Good Rod.
finneon evolves into lumineon
There are some fishermen on the edge of the route that leads to sunnyshore. The second one closest to where you entered the route has finneon. He has 4 Pokemon magikarp, finneon, remoraid, and gyradose. all near level 40