You can get one from Copycat in Saffron City or buy one at the Celadon department store.
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2 things: If used in battle the pokedoll allows you to escape no matter what, If used in the fight against the marowak ghost in Pokemon tower you can use the pokedoll to cheat past it instead of getting the silph scope.
at the Pokemon fan club house in vermilion.
You can buy a Pokedoll at the Celadon City Dept. Store on the 4th floor, it's the first item. Costs: 1000
A Pokedoll is in the Celadon Department Store.
Well, a pokedoll, eh? I can tell you. If you're just starting out, work hard and reach the pokedoll. If you have been to Lavender Town, take the route on the left near the Pokemon Center. Keep following the route. You'll be in Celadon City before you know it! ( Not Cerulean City where Misty is, by the way! ) Somewhere you'll find a big, big, big, big, big store and go in a door. Take the lift. Click Floor 4 and your Game Boy will start to shake a little bit. Ding dong! Walk out of the lift. Talk to the guy near at the bottom. The first item you can buy will be a useful pokedoll! Pokedolls distract wild pokemon if you can't get away. Suppose you meet a Geodude. You press RUN. Uh oh! You can't get away! Geodude uses a attack to weaken your pokemon! Act quickly! Press ITEM and pokedoll. It will distract him and you can leg it! Even if the pokemon is a boy, it will turn into a girly boy and play with the pokedoll! You'll get your pokedoll back after your battle, so be sure to pick one up! Hope this helped! :o)