You can buy a Pokedoll at the Celadon City Dept. Store on the 4th floor, it's the first item. Costs: 1000
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You can get one from Copycat in Saffron City or buy one at the Celadon department store.
2 things: If used in battle the pokedoll allows you to escape no matter what, If used in the fight against the marowak ghost in Pokemon tower you can use the pokedoll to cheat past it instead of getting the silph scope.
No you can only get it once in Pokemon mansion.
at the Pokemon fan club house in vermilion.
A Pokedoll is in the Celadon Department Store.