2 things: If used in battle the pokedoll allows you to escape no matter what, If used in the fight against the marowak ghost in Pokemon tower you can use the pokedoll to cheat past it instead of getting the silph scope.
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You can get one from Copycat in Saffron City or buy one at the Celadon department store.
at the Pokemon fan club house in vermilion.
You can buy a Pokedoll at the Celadon City Dept. Store on the 4th floor, it's the first item. Costs: 1000
A Pokedoll is in the Celadon Department Store.
it makes u have an easy get away from wild Pokemon just like the pokedoll and smoke ball