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Unfortunately You can't find a vaporeon anywhere in the game. You can however evolve an eevee you get from Bebe using a water stone. There are alternate Pokemon you can get from evolution:
- flareon-fire stone
- jolteon-thunderstone
- glaceon-level up near the icy rock
- leafeon-level up near the mossy rock
- umbreon-boost it's happiness to the max and then level up at night
- espeon-boost it's happiness to the max and then level up during the day
u can find flareon, jolteon, and vaporeon with a trainer around route 214.
Umbreon, leafeon and espeon with trainer on route 212.
glaceon with trainer on route 217
for more help filling your Sinnoh Pokedex head to http://pokemonplatinum.net/v2/pokedex/
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