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Vespiquen learns Defend Order at Level 13, But since a Female Combee doesn't evolve until level 21, You have to get a Heart Scale and get Defend Order through the Move Tutor.
A Combee will evolve at level 21 to a Vespiquen
A female Combee will evolve into Vespiquen at level 21.
No, there is no way through training, tutoring or breeding to make Dragonite learn sky attack.