37
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At level 37
Vespiquen learns Defend Order at Level 13, But since a Female Combee doesn't evolve until level 21, You have to get a Heart Scale and get Defend Order through the Move Tutor.
In Pokémon Diamond, Gabite will need to go to the Move Remember's in the order of not knowing Tackle, Sand-attack, Dragon Rage, Sandstorm, Take Down or Sand Tomb however it'll learn Slash at Level 28, Dragon Claw at Level 33, Dig at Level 40 and Dragon Rush at Level 49. Garchomp will need to go to the Move Remember in the event of not knowing Tackle, Fire Fang, Sand Attack, Sandstorm, Dragon Rage, Sand Tomb, Take Down, Slash, Dragon Claw and Dig however it will learn Crunch at Level 48 and it will alsao learn Dragon Rush at Level 55.
Unfortunately, Nidoking doesn't learn Horn Drill at all. In order to have your Nidoking learn Horn Drill, you'll need to level up your Nidorino to level 46 (you learn Horn Drill at that level) and then evolve it into a Nidoking.
Unfortunately, Arcanine does not learn Flamethrower. Your must level your Growlithe up to lv 50 to learn Flamethrower and then evolve it to Arcanine in order for Arcanine to have the move.