Vespiquen learns Defend Order at Level 13, But since a Female Combee doesn't evolve until level 21, You have to get a Heart Scale and get Defend Order through the Move Tutor.
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Unfortunately, Nidoking doesn't learn Horn Drill at all. In order to have your Nidoking learn Horn Drill, you'll need to level up your Nidorino to level 46 (you learn Horn Drill at that level) and then evolve it into a Nidoking.
Unfortunately, Arcanine does not learn Flamethrower. Your must level your Growlithe up to lv 50 to learn Flamethrower and then evolve it to Arcanine in order for Arcanine to have the move.
In order to evolve Piloswine must learn the move Ancient Power. Once it has learned that move, level it up and it will evolve into Mamoswine