Hitmonchan learns Mega Punch at Level 41.
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Hitmonchan learns ThunderPunch at level 31.
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In Pokémon LeafGreen, Hitmonchan's moves are ThunderPunch, Fire Punch, Ice Punch, Mega Punch, Comet Punch, Revenge, Pursuit, Agility, Mach Punch, Sky Uppercut, Detect, Counter, Bulk Up, Toxic, Focus Punch, Sunny Day, Hidden Power, Protect, Rain Dance, Earthquake, Return, Frustration, Brick Break, Double Team, Rock Tomb, Secret Power, Facade, Attract, Rest, Thief, Strength and Rock Smash.
Mankey doesn't learn this technique naturally, but you can teach him TM01 (Mega punch) at any level.
Hitmonlee is more defencive and Hitmonchan is high in attack. Hitmonchan also learns and the punches: ice punch, fire punch, and thunder punch