it does not learn thunderbolt on its own. you must teach it thunderbolt with TM24
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You can't get an HTM for thunderbolt if that's what you mean. Usually pokemon come with the skill thunderbolt like an ampharos, my ampharos learned discharge, thunderbolt, thunderpunch, and recharge. Also a large amount of electric pokemon come with this move or earn this move from evolving.
It dos'nt learn thunderbolt
Manectric can learn TM24- Thunderbolt.
Jolteon cannot learn Thunderbolt through leveling up. It can, however, learn Thunderbolt with the use of a TM.
It can learn Thunderbolt through TM.