Luxray does not learn Thunderbolt by leveling, however it can be taught it using TM24.
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it does not learn thunderbolt on its own. you must teach it thunderbolt with TM24
no luxray cannot learn the move thunderpunch but he can learn the move thunder fang
It dos'nt learn thunderbolt
Luxray does not learn charge beam by itself, you must use TM57, which holds charge beam, on your Luxray.
Manectric can learn TM24- Thunderbolt.