Luxray does not learn charge beam by itself, you must use TM57, which holds charge beam, on your Luxray.
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He never does. Luxray is a physical attacker, why on earth would you want Hyper Beam on it ??
Thunder(Tech machine) Thunder fang bite hyper beam charge beamLuxray can learn thunder fang at level 42, discharge at level 56, scary face level 49, That is all I can remember and having my luxray take in. I beat the elite four with him and my starter only.
thunder fang tunder discharge c harge beam
dragonair can learn ice beam any level
Lapras will learn Ice Beam at level 31.