He/She can learn
That's all the ones I know but please improve if you can!
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Piplup learns moves such as Growl, Bubble, Water Sport, Peck, Bide, Bubblebeam, Fury Attack, Brine, Whirlpool, Mist, Drill Pick and Hydro Pump.
in think lvl 43, after that, he won't learn any moves
Piplup learns Peck at level 15
out of piplup, chimchar and tutwig it would be PIPLUP! Piplup ca use water moves on chimchar, and ice moves on turtwig. the second is turtwig and third is chimchar. (I chose piplup and now it's a strong lv 100 Empoleon now!) PS: "Give it a try!"
lvl 6 or 7