in think lvl 43, after that, he won't learn any moves
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level up Ralts to 20 let it evolve then and then 30 to Gardevoir. I find it easier if yo let ralts level up to 29(better if you have an everstone) let it evolve then to 30.
at level 32, only because it learns double-hit. if you don't let aipom learn this move. it won't evolve.
Electabuzz doesn't evolve through level, you need to let it hold an item called an Electrizer and then trade it to another game.
To get Metagross, make sure you have a Beldum. Then raise it so it can evolve into Metang. Then evolve it at level 45 but I rather make it evolve at level 50 because Metang can learn the move Meteor Mash then let it evolve into Metagross.
When Tangela wants to learn Ancient power let it learn it, then level it up again and he/she will evolve into Tangrowth.