Piplup learns Peck at level 15
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Drill Peck is not a TM, but if you want this move, start with a piplup and your empoleon can learn it.
Piplup learns moves such as Growl, Bubble, Water Sport, Peck, Bide, Bubblebeam, Fury Attack, Brine, Whirlpool, Mist, Drill Pick and Hydro Pump.
It should learn Drill Peck at around level 58.
It'll learn Drill Peck at level 47.
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