lvl 6 or 7
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Drill Peck is not a TM, but if you want this move, start with a piplup and your empoleon can learn it.
Piplup learns Peck at level 15
No, it doesn't sadly. Until level 16 (When it evolves)does it learn a new move. The new move Abra learns is Confusion after it evolves.
piplup totodile squrtile mudkip
Piplup and Squirtle are both as good as each other, although in my opinion Squirtle is better. Piplup is Definitely a close comeback to Squirtle because at Empoleon it has two types which are a good combo, leaving less weaknesses and more strengths. Squirtle is better because it has a good attack and an awesome defence at Blastoise. Blastoise can also learn a move called shell bash or skull bash which is a two turn move increasing defence on the first turn and attacking on the second with 150 power.