Net ball.
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The best Pokemon in Pokemon Sapphire is usually known as Kyogre. Kyogre can be found in The Cave of Origin. Or once u beat the Pokemon league dnt use ur poke ball on kyogre and go to the sky piller and catch rayquazer lvl 70
To catch Kyoger with out a master ball weeken him a liltel bit or paralize confuse burn or freeze him and use net and dive balls.NEVER WASTE A MASTER BALL ON KYOGER!
The best ball to catch Giratina is the Master Ball but the next best and effective options would be the Dusk Ball or the Ultra Ball.
I captured Kyogre by weakening it and after using (and failing with) Ultra Balls, I used a Great Ball and caught it.
the ultra ball is what i used to catch it...but you could use the master ball after you get it