the ultra ball is what i used to catch it...but you could use the master ball after you get it
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by throwing it
best ball is always a master ball but i would use a poke ball cause you meet at level 1 just teach faise swipe to a Pokemon use it and use a couple poke balls
probably ultra or time or speed depending on how quick you try to catch it
That would be a Master Ball, however, if you don't have it no more, or want to save it, use a duskball or a Ultraball
master ball. but save it if you want it to use it on entei or raioku which run in the wild