To catch Kyoger with out a master ball weeken him a liltel bit or paralize confuse burn or freeze him and use net and dive balls.NEVER WASTE A MASTER BALL ON KYOGER!
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I captured Kyogre by weakening it and after using (and failing with) Ultra Balls, I used a Great Ball and caught it.
Look at it this way, if you try catching Kyogre ( full health, no status changes, and no master ball.) with a regular poke'ball, you will catch it right off the bat! your welcome.
there are 2 master ball s and a master ball is rare you can only use it for kyogre requaza groudon salmence fly gon and the rest of the strongest Pokemon a master ball always captures a Pokemon no Pokemon can break out its in possible
Net ball.
The best Pokemon in Pokemon Sapphire is usually known as Kyogre. Kyogre can be found in The Cave of Origin. Or once u beat the Pokemon league dnt use ur poke ball on kyogre and go to the sky piller and catch rayquazer lvl 70