Master LOL
really , i recommend quick balls, then ultra,then timer.
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You do if you want to catch the female Zoroark event. However, if you have a Celbi and get the Zorua,you can evolve it in to a Zoroark.
The best ball to catch Giratina is the Master Ball but the next best and effective options would be the Dusk Ball or the Ultra Ball.
you cannot catch it. but you can breed zoroark to get it as an egg.
Net ball.
the ultra ball is what i used to catch it...but you could use the master ball after you get it