You have to do a local or online trade with someone to get Politoed. Trade a Poliwhirl that's holding a King's Rock and it will evolve upon arrival :)
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king's rock evolves poliwhirl into politoed and slowpoke into slowking when they are traded
you have to give it a moon stone if you want it to evolve it into politoed give it a sun stone
Poliwhirl evolves into poliwrath when you use a Water Stone on it. It can also evolve into politoed if you give it a King's Rock to hold and trade it. It does not evolve by level.Poliwhirl evolves into poliwrath when you use a Water Stone on it. It can also evolve into a politoed if you trade it while it's holding a King's Rock.Poliwhirl does not evolve at a level. Poliwhirl can evolve into poliwrath with a water stone, or poliwhirl can evolve into politoed when it is traded while holding a kings rock.Hope I helped!
Poliwrath is good when you use it for battles against wild pokemon, trainers and gym leaders. Politoed in the other hand is better when it comes to the contests. Poliwhirl evolves to Poliwrath when you expose it to a water stone while it can also evolve into a Politoed when you trade it holding a King's rock. Overall I would recommend a Poliwrath because it is dual type and is stronger. It will get STAB on fighting type moves.
poliwhirl has to be traded with a kings rock to get politoed