Have a ditto hold it as an item and its defense will rise!
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Metal Powder is a Ditto-exclusive item. If Ditto is given Metal Powder, its defenses will become 150% of what they normally are. Unfortunately, the effects are null and void as soon as it uses Transform.
Sleep powder is a move that can be learned by most grass type Pokemon sleep powder is not a move taught by a regular move tutor nor is it a TM you can though teach the Pokemon sleep powder if it can learn it from the super move tutor on two island.
the Pokemon that evolve with metal coat are steelix and scisor
sleep powder catch a butter free and level it up afew times then it will try to learn sleep powder
they are both great moves sleep powder is good for catching Pokemon leach seed is good in battles when you need hp