When you beat the game with the green knight you will get the royal guard which is the character with chains covering his face and sand colored armor. you find him in the desert levels. and if you beat the game with the royal guard then you will get the saracen which is the brown guy that can make a sand tornado and make a wind of sand, he has straps of cloth on his head and body making him a desert fighter.
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i heard some one say you bypass the city and beat crasher wake then shell be there without finding her or you can try to find her your choice. I cant find her ether i beat crasher wake and shes still not there.....
to get into n castle you have to beat the elite 4
The best character is completely based on how you play. The Orange knight is the strongest if that's what you mean. But, out of every character in the game including downloads and unlockables the presets are actually the best.The Blue Knight can freeze enemies but doesn't do much damage, so I recommend that to more adept players.The Red Knight can continuously zap enemies and does an average amount of damage, I would suggest that to new players.The Orange Knight does the highest amount of damage, so he's okay for people who have already beat the game or first time players.The Green Knight does corrosive damage (continues damaging after hit) so that would be moreover if you're used to the game.
If you are talking about Defog(HM05), then you will have to beat Crasher Wake first in order to use it outside of battle. It is somewhere in the Great Marsh. In Platinum, it's Fantina, and after you beat her, you can use Surf.