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If you are talking about Defog(HM05), then you will have to beat Crasher Wake first in order to use it outside of battle. It is somewhere in the Great Marsh.

In Platinum, it's Fantina, and after you beat her, you can use Surf.

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Q: How do you get the 5th HM move in diamond?
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Related questions

Where do you get the move to move boulders in Pokemon diamond?

you mest get the hm strength.

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The move Rock Tomb is a TM, not a HM.

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go to route 217.

Is there a HM remover on Pokemon Diamond?

yes in canalave city there is a move deleter

Where can you delete HM's on Pokemon diamond?

Go to the move deleter in Canalave City

What is the HM for Pokemon Diamond ds?

A HM is a tool that teaches your Pokemon an attack move and to move outside a battle, for example cut. HMs can not be erased from your pokemons memory.

Were did you get HM dive in Pokemon Diamond?

on Pokemon dimond there isn't a move caled dive. but there are a hm called surf and cant

How do you move boulders in mount cornet Pokemon diamond?

easy you get the hm strength and then you can move all the bolders you need to

How do you delete hm's in diamond and pearl?

Go to the move deleter in Canalva City.

Is it possible to make the move surf on Pokemon diamond unlimited?

surf is a hm. It is unlimited.

Cam you get a deleted hm move back on diamond?

there is a man in a house in the steel gym town

How do you move a rock in Pokemon diamond?

you have to get the hm strength then beat the gym leader in canalave city