Most Pokemon can learn that move think of it this way Pokemon that have hands can learn it some Pokemon learn it from the move tutors however some can learn it via egg move only.
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I am pretty sure your Pokemon can learn it on a high level. :)
You can't. Only in the second generation (gold, silver, crystal) it's TM41. In Diamond and Pearl is their no Thunder Punch TM. You can learn Thunder Punch in Pokemon Platinum from the Move Tutor.
The only way Alakazam can learn Fire Punch is through a Move Tutor on Pokemon Emerald Version.
There is no TM for thunder punch.
there is no TM for thunderpunch but Pokemon like electivire or medicham can learn it.