Fighting/Pshychic Pokemon can learn it. Medicham learns them.
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Thunder Punch, Fire Punch, Outrage, and either Fly or Ice Punch.
Of all unfortunate things you can't get ice punch or fire punch or thunder punch, all of the punches must be learned by a Pokemon that can by level.
Hitmonlee is more defencive and Hitmonchan is high in attack. Hitmonchan also learns and the punches: ice punch, fire punch, and thunder punch
lets see. well first you need a medicham teach it Meditate fire/ice punch NOT thunder punch doesn't matter didn't you read the above!
It learns thunder punch,fire punch,and ice punch from the move teacher. The other moves it learns dizzy punch,knock off, confuse ray, stomp, SuperPower, zen headbutt, crush grip, and giga impact. Crush Grip is its signature move. Regigigas might be able to learn mega punch.