Dark Void- foe:1(both in a double battle.)
Grass Whistle- foe:1
Hypnosis foe:1
Lovely Kiss- foe:1
Secret Power(Secret Power has a 30% chance to cause sleep when used in tall grass. Power:70)
Sing- foe:1
Sleep Powder- foe:1
Rest(The user falls asleep for 2 turns but also fully restores HP and status.)
Yawn(The opponent will fall asleep a turn after this move.)(Hit's ghost types.)
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The Pokémon moves that will cause opponents to fall asleep would include Dark Void, Hypnosis, Grass Whitely, Lovely Kiss, Sleep Powder, Spore, Yawn and Dark Void is a move that will put multiple targets to sleep at the same time additionally the move of "Rest" can put the user to sleep in order to heal itself including the healing of any current status issues and it will wake up within two turns.
sleep powder catch a butter free and level it up afew times then it will try to learn sleep powder
Water Pokemon with water attacks or Grass Pokemon with Grass attacks
Well, you can't really. it matters on your pokemons speed and evaiseness. it happens randomly
Fire Pokemon
the Pokemon that is good angensti electric type is ground attacks or rock attacks. just get a Pokemon that can learn earthquake and use it on the electric or the fire type Pokemon.