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Go to Blackthorn City and go inside the house right next to the Pokemart. Talk to the old man and he will teach your Blaziken Blast Burn, but only if it has full happiness.

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Q: How do you teach Blaziken blast burn in Pokemon soulsilver?
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How teach Blaziken blast burn in Pokemon emerald?

Sorry. Blaziken is the only Fire type starter that does not learn Blast Burn


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