I'm afraid that you cant make or get Pokéblocks on Leaf Green/Fire Red
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There are no PokeBlocks in HG/SS.
If you put Soothe Bell on a Pokemon or give it Pokeblocks.
Pokemon can only have a set number of pokeblocks. Once they have eaten that set number, they will never be able to eat any more. The only way that you can get your pokemon all the way to the highest amount of a skill is to make really good pokeblocks.
Depends on it's nature allthough usually it likes blue pokeblocks or pokeblocks with dry qualities.
This happens. If you gave your pokemon alot of pokeblocks, it will not eat anymore. Which means; It's done forever. You will never be able to give your pokemon a pokeblock.