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You get one on the boat. When you complete the Elite Four (you need to beat all 8 badges, then swim to the right in New Bark Town and so on... Then pwn Elite Four and the Champion. They have pretty tough Pokèmon), you get a call from Elm, and he gives you a ticket. Go to Olivine, and go to the port. A sailor will ask you for the ticket, and you'll end up on the boat after all. You complete a little quest there (this is another story; albeit it involves finding a girl and stuff), and a guy gives you a Metal Coat as a thanks. The boat will then arrive to Kanto.

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15y ago
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Q: How do you get metal coat in Pokemon Gold?
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