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There is no way for you to get Headbutt in Pokémon Diamond unless a Pokémon actually learns the move by itself and the only ones who learn Headbutt through leveling up are Slowpoke, Slowbro, Slowking, Seel, Dewgong, Drowzee, Hypno, Cubone, Marowak, Snubbull, Granbull, Mantyke, Mantine, Zigzagoon, Linoone, Shroomish, Breloom, Aron, Lairon, Aggron, Snorunt, Glalie, Bagon, Shelgon, Salamence, Bidoof, Bibarel, Cranidos and Rampardos.

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Q: How do you get headbutt in Pokemon Diamond?
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