There is no way for you to get Headbutt in Pokémon Diamond unless a Pokémon actually learns the move by itself and the only ones who learn Headbutt through leveling up are Slowpoke, Slowbro, Slowking, Seel, Dewgong, Drowzee, Hypno, Cubone, Marowak, Snubbull, Granbull, Mantyke, Mantine, Zigzagoon, Linoone, Shroomish, Breloom, Aron, Lairon, Aggron, Snorunt, Glalie, Bagon, Shelgon, Salamence, Bidoof, Bibarel, Cranidos and Rampardos.
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headbutt????????????? )-:)
Headbutt dosn't come in a TM. You can teach a pokemon Headbutt by talking to a guy in a pink shirt in the Illex Forest. You can Headbutt trees (Like an HM) to find certain PoKeMoN.(It vairies where you Headbutt.)
I don't know all of the Pokemon that can learn Headbutt, but I know that Cubone can learn it.
You have to go to Mount Silver and headbutt the trees on the left of the Pokemon center. P.S. you may also run into a herecross too if you headbutt trees.Aipoms are uncommon and can be found by headbutting treesFirst, this is under relationships, and Pokemon Diamond, Pearl, and Platinum. Aipom is found uncommonly when you headbutt trees, there is a specific one, but I'll change my answer to be more specific when you change your question.
teach a Pokemon headbutt and use it on small trees teach a Pokemon headbutt and use it on small trees