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You have to go to Mount Silver and headbutt the trees on the left of the Pokemon center. P.S. you may also run into a herecross too if you headbutt trees.
Aipoms are uncommon and can be found by headbutting trees
First, this is under relationships, and Pokemon Diamond, Pearl, and Platinum. Aipom is found uncommonly when you headbutt trees, there is a specific one, but I'll change my answer to be more specific when you change your question.

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