You cnnot catch it in Pokemon fire red ,but you can catch it in Pokemon Diamond and Pearl.If you want it to be in your fire red,you will have to migrate it from your Diamond/pearl to your fire red.
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rotom isn't in Pokemon emerald
Rotom is an Electric/Ghost-type Pokemon that is #479 in the National Pokedex. It has the ability to change in multiple forms - Heat Rotom, Wash Rotom, Frost Rotom, Fan Rotom, and Mow Rotom - that all have different secondary typing in addition to Electric.
No trainer have Rotom in Pokemon Pearl, Diamond, or Platinum.
In Pokemon firered you can't, but in Pokemon leafgreen you can get it then trade it to Pokemon firered.
You can get rotom from Pokemon diamond, pearl & platinum, or if you have an action replay, pokesav it or wild modify it.