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You must first place the Odd Keystone in the Hallowed Tower. Then you must meet 30 different people in the Underground. Afterwards, a Spiritomb should appear at the Hallowed Tower. Save in front of it and talk to it. If it is not shiny, then keep reseting your game until it is.
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Earn +20 ptsQ: How do you catch shiny Spiritomb?
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