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Firstly, I strongly recommend coming with some sort of a Grass type Pokemon. This way the Starmie won't annihilate your Pikachu. Secondly, level up your Pikachu to level 22 so it stands more of a chance. Thirdly, the walkthrough:

  1. With your new Grass type Pokemon in hand (about level 22-25 I hope) start your battle with Misty.
  2. Knock out Staryu with your Pikachu, and then fight to the death with Starmie. Though I highly doubt you will survive against the Starmie (with Misty's Super Potions and all), if you defeat it disregard the Grass type Pokemon (or keep it, whichever you wish).
  3. After your Pikachu most probably gets defeated by the Starmie, switch to your Grass type Pokemon and batter the Starmie with your best moves to defeat it.
  4. If you still can't defeat Misty with these tactics, just train your Pikachu and your Grass type Pokemon more.

5. : if all those things fail train your charmander or charmeleon to lv 24 at least and keep using scratch and scratch and scratch till charmander is knocked out then switch to pikachu or the grass type GOOD LUCK! ps-this was not writen by the message writer this was writen by me who is going to improve the answer

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Q: How do you beat misty with a lv 20 Charmander and a lv 20 Pikachu in Pokemon fire red?
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