Beat the elite four then the guy blocking thepath to it will go away.
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You can find Duskull on Route 224. :)
in Route 224
on route 224 Edit: But Dawns lil Sister has to say Route 224! They said theres a whole bunch of Natu's There.
The event scene in Pokemon Pearl where the player meets Professor Oak on route 224 is part of a Nintendo-sponsored special event in order to obtain the legendary Pokemon, Shaymin. The player must be involved in the special event to obtain the key item called Oak's Letter, and afterwards Professor Oak will appear on route 224.
After Obtaining National Pokedex, Beautifly can be found at Eterna Forest, Route 224 and Route 230 they are RARE