in Route 224
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At the beginning of the game, Professor Oak is in Mr. Pokemon's house. Mr. Pokemon's house is north of Cherrygrove City. After that, Professor Oak is in Pallet Town in his Pokemon lab.
What the hell is a Pokemon crystal
The event scene in Pokemon Pearl where the player meets Professor Oak on route 224 is part of a Nintendo-sponsored special event in order to obtain the legendary Pokemon, Shaymin. The player must be involved in the special event to obtain the key item called Oak's Letter, and afterwards Professor Oak will appear on route 224.
well, he should be at route 221 for Pokemon pearl and diamond
After seeing all the Pokemon in the Sinnoh Dex go talk to Professor Rowan and Professor Oak will come and give you the pokeradar as well as the National Dex.