on route 224
Edit: But Dawns lil Sister has to say Route 224! They said theres a whole bunch of Natu's There.
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You can get natu and xatu (the evolved form of natu) in the safari zone near fortree city
Natu evolves at level 25.
To get Natu you have to pass through the door in the right in the mansion in route 212.
You can get natu at the ruins of alph in heart gold and soul silver
You cannot catch Natu in Pokemon Black. You will have to trade for one or transfer one from a DS Series game.