No, but he does get close. A girl named Lykoko does like him & she does ask him to marry her. Brock overjoyed at the idea says yes. It turns out later that Lykoko is an illusion created by ninetails & Brock is unfortunately awakened from ninetail's spell.
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Well, from all the episodes I've seen from 'Sinnoh Leauge Victors' I haven't seen Brock kiss anyone. But from 'Galactic Battles' I still haven't seen Brock kiss anyone, and from 'Black And White' I don't even think he's in the show! So my answer is; No, Brock has not kissed anyone, but he has tried to but his attempt at trying get killed by one of his Pokemon which uses one of it's move which is poisonus and stings Brock! So poor Brock may never date or kiss anyone D: :(
yes everyone has a surname even in pokemon and brock also has one but it is not mentioned in the pokemon anime
You can catch a grass type Pokemon but catching mankey is the easiest because it appears a lot especially to the east of Pewter (where Brock is). Mankey has the advantage of being a fighting Pokemon which is super-effective against Brock's Pokemon.
Onix.
Brock sings several too many times to list.